Semiconductor processing chamber for improved precursor flow

ABSTRACT

Exemplary semiconductor processing systems may include a processing chamber, and may include a remote plasma unit coupled with the processing chamber. Exemplary systems may also include an adapter coupled with the remote plasma unit. The adapter may include a first end and a second end opposite the first end. The adapter may define an opening to a central channel at the first end, and the central channel may be characterized by a first cross-sectional surface area. The adapter may define an exit from a second channel at the second end, and the adapter may define a transition between the central channel and the second channel within the adapter between the first end and the second end. The adapter may define a third channel between the transition and the second end of the adapter, and the third channel may be fluidly isolated from the central channel and the second channel.

CROSS-REFERENCES TO RELATED APPLICATIONS

This application claims priority to U.S. Provisional Application No. 62/507,533, filed May 17, 2017, the disclosure of which is hereby incorporated by reference in its entirety for all purposes.

TECHNICAL FIELD

The present technology relates to semiconductor systems, processes, and equipment. More specifically, the present technology relates to systems and methods for delivering precursors within a system and chamber.

BACKGROUND

Integrated circuits are made possible by processes which produce intricately patterned material layers on substrate surfaces. Producing patterned material on a substrate requires controlled methods for removal of exposed material. Chemical etching is used for a variety of purposes including transferring a pattern in photoresist into underlying layers, thinning layers, or thinning lateral dimensions of features already present on the surface. Often it is desirable to have an etch process that etches one material faster than another facilitating, for example, a pattern transfer process or individual material removal. Such an etch process is said to be selective to the first material. As a result of the diversity of materials, circuits, and processes, etch processes have been developed with a selectivity towards a variety of materials.

Etch processes may be termed wet or dry based on the materials used in the process. A wet HF etch preferentially removes silicon oxide over other dielectrics and materials. However, wet processes may have difficulty penetrating some constrained trenches and also may sometimes deform the remaining material. Dry etch processes may penetrate into intricate features and trenches, but may not provide acceptable top-to-bottom profiles. As device sizes continue to shrink in next-generation devices, the ways in which systems deliver precursors into and through a chamber may have an increasing impact. As uniformity of processing conditions continues to increase in importance, chamber designs and system set-ups may have an important role in the quality of devices produced.

Thus, there is a need for improved systems and methods that can be used to produce high quality devices and structures. These and other needs are addressed by the present technology.

SUMMARY

Exemplary semiconductor processing systems may include a processing chamber, and may include a remote plasma unit coupled with the processing chamber. Exemplary systems may also include an adapter coupled with the remote plasma unit. The adapter may include a first end and a second end opposite the first end. The adapter may define an opening to a central channel at the first end, and the central channel may be characterized by a first cross-sectional surface area. The adapter may define an exit from a second channel at the second end, and the adapter may define a transition between the central channel and the second channel within the adapter between the first end and the second end. The adapter may define a third channel between the transition and the second end of the adapter, and the third channel may be fluidly isolated from the central channel and the second channel within the adapter.

In some embodiments, the second channel may be characterized by a second cross-sectional area less than the first cross-sectional area. The second channel may include a plurality of channels extending from the central channel. The adapter may further define a port providing access to the third channel. The systems may further include an isolator coupled between the adapter and the processing chamber. The isolator may include an annular member about an isolator channel, and the isolator channel may be fluidly coupled with the second channel and the third channel. In some embodiments, the isolator may include a ceramic material. The systems may also include a mixing manifold coupled between the isolator and the processing chamber. The mixing manifold may be characterized by an inlet having a diameter equal to a diameter of the isolator channel. In embodiments the inlet of the mixing manifold may transition to a tapered section of the mixing manifold. The tapered section of the mixing manifold may transition to a flared section of the mixing manifold extending to an outlet of the mixing manifold.

The present technology also includes semiconductor processing systems. The systems may include a remote plasma unit, and may also include a processing chamber. The processing chamber may include a gasbox defining a central channel. The processing chamber may include a blocker plate coupled with the gasbox, and the blocker plate may define a plurality of apertures through the blocker plate. The processing chamber may include a faceplate coupled with the gasbox at a first surface of the faceplate. The processing chamber may also include an ion suppression element coupled with the faceplate at a second surface of the faceplate opposite the first surface of the faceplate.

In some embodiments, the system may also include a heater coupled externally to the gasbox about a mixing manifold coupled to the gasbox. The gasbox may define a volume from above and the blocker plate may define the volume from below and about an outer radius. In embodiments, the gasbox, faceplate, and ion suppression element may be directly coupled together. In some embodiments, the faceplate may be characterized along a vertical cross-section of the faceplate by a first diameter and a second diameter, and the faceplate may define a ledge on an interior of the first surface of the faceplate extending to an internal region of the faceplate characterized by the second diameter. The blocker plate may extend into the internal region of the faceplate, and the blocker plate may be characterized by a diameter within five percent of the second diameter. The first surface of the faceplate and the second surface of the faceplate may be characterized by the first diameter. In some embodiments, the gasbox may define a plurality of annular trenches along a surface of the gasbox in contact with the faceplate, and the ion suppression element may define a plurality of annular trenches along a surface of the ion suppression element in contact with the faceplate.

The present technology also encompasses methods of delivering precursors through a semiconductor processing system. The methods may include forming a plasma of a fluorine-containing precursor in a remote plasma unit. The methods may include flowing plasma effluents of the fluorine-containing precursor into an adapter. The methods may include flowing a hydrogen-containing precursor into the adapter, and the adapter may be configured to maintain the plasma effluents of the fluorine-containing precursor and the hydrogen-containing precursor fluidly isolated through the adapter. The methods may also include flowing the plasma effluents of the fluorine-containing precursor and the hydrogen-containing precursor into a mixing manifold configured to mix the plasma effluents of the fluorine-containing precursor and the hydrogen-containing precursor. In some embodiments, the methods may also include flowing the mixed plasma effluents of the fluorine-containing precursor and the hydrogen-containing precursor into a processing chamber.

Such technology may provide numerous benefits over conventional systems and techniques. For example, by directly coupling the chamber components, a more uniform heating may be provided through the chamber to limit or prevent particulate deposition on chamber components. Additionally, by utilizing components that produce etchant species outside of the chamber, mixing and delivery to a substrate may be provided more uniformly over traditional systems. These and other embodiments, along with many of their advantages and features, are described in more detail in conjunction with the below description and attached figures.

BRIEF DESCRIPTION OF THE DRAWINGS

A further understanding of the nature and advantages of the disclosed technology may be realized by reference to the remaining portions of the specification and the drawings.

FIG. 1 shows a top plan view of an exemplary processing system according to embodiments of the present technology.

FIG. 2A shows a schematic cross-sectional view of an exemplary processing chamber according to embodiments of the present technology.

FIG. 2B shows a detailed view of an exemplary showerhead according to embodiments of the present technology.

FIG. 3 shows a bottom plan view of an exemplary showerhead according to embodiments of the present technology.

FIG. 4 shows a schematic cross-sectional view of an exemplary processing system according to embodiments of the present technology.

FIG. 5A illustrates a schematic perspective view of a blocker plate according to embodiments of the present technology.

FIG. 5B illustrates a schematic flow profile through a blocker plate according to embodiments of the present technology.

FIG. 6 shows a schematic partial cross-sectional view of an exemplary processing chamber according to embodiments of the present technology.

FIG. 7 shows operations of a method of delivering precursors through a processing chamber according to embodiments of the present technology.

Several of the figures are included as schematics. It is to be understood that the figures are for illustrative purposes, and are not to be considered of scale unless specifically stated to be of scale. Additionally, as schematics, the figures are provided to aid comprehension and may not include all aspects or information compared to realistic representations, and may include exaggerated material for illustrative purposes.

In the appended figures, similar components and/or features may have the same reference label. Further, various components of the same type may be distinguished by following the reference label by a letter that distinguishes among the similar components. If only the first reference label is used in the specification, the description is applicable to any one of the similar components having the same first reference label irrespective of the letter.

DETAILED DESCRIPTION

The present technology includes semiconductor processing systems, chambers, and components for performing semiconductor fabrication operations. Many dry etch operations performed during semiconductor fabrication may involve multiple precursors. When energized and combined in various ways, these etchants may be delivered to a substrate to remove or modify aspects of a substrate. Traditional processing systems may provide precursors, such as for etching, in multiple ways. One way of providing enhanced precursors or etchants is to provide all of the precursors through a remote plasma unit before delivering the precursors through a processing chamber and to a substrate, such as a wafer, for processing. An issue with this process, however, is that the different precursors may be reactive with different materials, which may cause damage to the remote plasma unit. For example, an enhanced fluorine-containing precursor may react with aluminum surfaces, but may not react with oxide surfaces. An enhanced hydrogen-containing precursor may not react with an aluminum surface within a remote plasma unit, but may react with and remove an oxide coating. Thus, if the two precursors are delivered through a remote plasma unit together, they may damage a coating or liner within the unit.

Traditional processing may also deliver one precursor through a remote plasma device for plasma processing, and may deliver a second precursor directly into a chamber. An issue with this process, however, is that mixing of the precursors may be difficult, and may not provide a uniform etchant at the wafer or substrate. This may cause processes to not be performed uniformly across a surface of a substrate, which may cause device issues as patterning and formation continues.

The present technology may overcome these issues by utilizing components and systems configured to mix the precursors prior to delivering them into the chamber, while only having one etchant precursor delivered through a remote plasma unit, although multiple precursors can also be flowed through a remote plasma unit, such as carrier gases or other etchant precursors. The particular bypass scheme may fully mix the precursors prior to delivering them to a processing chamber. This may allow uniform processes to be performed while protecting a remote plasma unit. Chambers of the present technology may also include component configurations that maximize thermal conductivity through the chamber, and increase ease of servicing by coupling the components in specific ways.

Although the remaining disclosure will routinely identify specific etching processes utilizing the disclosed technology, it will be readily understood that the systems and methods are equally applicable to deposition and cleaning processes as may occur in the described chambers. Accordingly, the technology should not be considered to be so limited as for use with etching processes alone. The disclosure will discuss one possible system and chamber that can be used with the present technology to perform certain of the removal operations before additional variations and adjustments to this system according to embodiments of the present technology are described.

FIG. 1 shows a top plan view of one embodiment of a processing system 100 of deposition, etching, baking, and curing chambers according to embodiments. In the figure, a pair of front opening unified pods (FOUPs) 102 supply substrates of a variety of sizes that are received by robotic arms 104 and placed into a low pressure holding area 106 before being placed into one of the substrate processing chambers 108 a-f, positioned in tandem sections 109 a-c. A second robotic arm 110 may be used to transport the substrate wafers from the holding area 106 to the substrate processing chambers 108 a-f and back. Each substrate processing chamber 108 a-f, can be outfitted to perform a number of substrate processing operations including the dry etch processes described herein in addition to cyclical layer deposition (CLD), atomic layer deposition (ALD), chemical vapor deposition (CVD), physical vapor deposition (PVD), etch, pre-clean, degas, orientation, and other substrate processes.

The substrate processing chambers 108 a-f may include one or more system components for depositing, annealing, curing and/or etching a dielectric film on the substrate wafer. In one configuration, two pairs of the processing chambers, e.g., 108 c-d and 108 e-f, may be used to deposit dielectric material on the substrate, and the third pair of processing chambers, e.g., 108 a-b, may be used to etch the deposited dielectric. In another configuration, all three pairs of chambers, e.g., 108 a-f, may be configured to etch a dielectric film on the substrate. Any one or more of the processes described may be carried out in chamber(s) separated from the fabrication system shown in different embodiments. It will be appreciated that additional configurations of deposition, etching, annealing, and curing chambers for dielectric films are contemplated by system 100.

FIG. 2A shows a cross-sectional view of an exemplary process chamber system 200 with partitioned plasma generation regions within the processing chamber. During film etching, e.g., titanium nitride, tantalum nitride, tungsten, silicon, polysilicon, silicon oxide, silicon nitride, silicon oxynitride, silicon oxycarbide, etc., a process gas may be flowed into the first plasma region 215 through a gas inlet assembly 205. A remote plasma system (RPS) 201 may optionally be included in the system, and may process a first gas which then travels through gas inlet assembly 205. The inlet assembly 205 may include two or more distinct gas supply channels where the second channel (not shown) may bypass the RPS 201, if included.

A cooling plate 203, faceplate 217, ion suppressor 223, showerhead 225, and a substrate support 265, having a substrate 255 disposed thereon, are shown and may each be included according to embodiments. The pedestal 265 may have a heat exchange channel through which a heat exchange fluid flows to control the temperature of the substrate, which may be operated to heat and/or cool the substrate or wafer during processing operations. The wafer support platter of the pedestal 265, which may comprise aluminum, ceramic, or a combination thereof, may also be resistively heated in order to achieve relatively high temperatures, such as from up to or about 100° C. to above or about 1100° C., using an embedded resistive heater element.

The faceplate 217 may be pyramidal, conical, or of another similar structure with a narrow top portion expanding to a wide bottom portion. The faceplate 217 may additionally be flat as shown and include a plurality of through-channels used to distribute process gases. Plasma generating gases and/or plasma excited species, depending on use of the RPS 201, may pass through a plurality of holes, shown in FIG. 2B, in faceplate 217 for a more uniform delivery into the first plasma region 215.

Exemplary configurations may include having the gas inlet assembly 205 open into a gas supply region 258 partitioned from the first plasma region 215 by faceplate 217 so that the gases/species flow through the holes in the faceplate 217 into the first plasma region 215. Structural and operational features may be selected to prevent significant backflow of plasma from the first plasma region 215 back into the supply region 258, gas inlet assembly 205, and fluid supply system 210. The faceplate 217, or a conductive top portion of the chamber, and showerhead 225 are shown with an insulating ring 220 located between the features, which allows an AC potential to be applied to the faceplate 217 relative to showerhead 225 and/or ion suppressor 223. The insulating ring 220 may be positioned between the faceplate 217 and the showerhead 225 and/or ion suppressor 223 enabling a capacitively coupled plasma (CCP) to be formed in the first plasma region. A baffle (not shown) may additionally be located in the first plasma region 215, or otherwise coupled with gas inlet assembly 205, to affect the flow of fluid into the region through gas inlet assembly 205.

The ion suppressor 223 may comprise a plate or other geometry that defines a plurality of apertures throughout the structure that are configured to suppress the migration of ionically-charged species out of the first plasma region 215 while allowing uncharged neutral or radical species to pass through the ion suppressor 223 into an activated gas delivery region between the suppressor and the showerhead. In embodiments, the ion suppressor 223 may comprise a perforated plate with a variety of aperture configurations. These uncharged species may include highly reactive species that are transported with less reactive carrier gas through the apertures. As noted above, the migration of ionic species through the holes may be reduced, and in some instances completely suppressed. Controlling the amount of ionic species passing through the ion suppressor 223 may advantageously provide increased control over the gas mixture brought into contact with the underlying wafer substrate, which in turn may increase control of the deposition and/or etch characteristics of the gas mixture. For example, adjustments in the ion concentration of the gas mixture can significantly alter its etch selectivity, e.g., SiNx:SiOx etch ratios, Si:SiOx etch ratios, etc. In alternative embodiments in which deposition is performed, it can also shift the balance of conformal-to-flowable style depositions for dielectric materials.

The plurality of apertures in the ion suppressor 223 may be configured to control the passage of the activated gas, i.e., the ionic, radical, and/or neutral species, through the ion suppressor 223. For example, the aspect ratio of the holes, or the hole diameter to length, and/or the geometry of the holes may be controlled so that the flow of ionically-charged species in the activated gas passing through the ion suppressor 223 is reduced. The holes in the ion suppressor 223 may include a tapered portion that faces the plasma excitation region 215, and a cylindrical portion that faces the showerhead 225. The cylindrical portion may be shaped and dimensioned to control the flow of ionic species passing to the showerhead 225. An adjustable electrical bias may also be applied to the ion suppressor 223 as an additional means to control the flow of ionic species through the suppressor.

The ion suppressor 223 may function to reduce or eliminate the amount of ionically charged species traveling from the plasma generation region to the substrate. Uncharged neutral and radical species may still pass through the openings in the ion suppressor to react with the substrate. It should be noted that the complete elimination of ionically charged species in the reaction region surrounding the substrate may not be performed in embodiments. In certain instances, ionic species are intended to reach the substrate in order to perform the etch and/or deposition process. In these instances, the ion suppressor may help to control the concentration of ionic species in the reaction region at a level that assists the process.

Showerhead 225 in combination with ion suppressor 223 may allow a plasma present in first plasma region 215 to avoid directly exciting gases in substrate processing region 233, while still allowing excited species to travel from chamber plasma region 215 into substrate processing region 233. In this way, the chamber may be configured to prevent the plasma from contacting a substrate 255 being etched. This may advantageously protect a variety of intricate structures and films patterned on the substrate, which may be damaged, dislocated, or otherwise warped if directly contacted by a generated plasma. Additionally, when plasma is allowed to contact the substrate or approach the substrate level, the rate at which oxide species etch may increase. Accordingly, if an exposed region of material is oxide, this material may be further protected by maintaining the plasma remotely from the substrate.

The processing system may further include a power supply 240 electrically coupled with the processing chamber to provide electric power to the faceplate 217, ion suppressor 223, showerhead 225, and/or pedestal 265 to generate a plasma in the first plasma region 215 or processing region 233. The power supply may be configured to deliver an adjustable amount of power to the chamber depending on the process performed. Such a configuration may allow for a tunable plasma to be used in the processes being performed. Unlike a remote plasma unit, which is often presented with on or off functionality, a tunable plasma may be configured to deliver a specific amount of power to the plasma region 215. This in turn may allow development of particular plasma characteristics such that precursors may be dissociated in specific ways to enhance the etching profiles produced by these precursors.

A plasma may be ignited either in chamber plasma region 215 above showerhead 225 or substrate processing region 233 below showerhead 225. In embodiments, the plasma formed in substrate processing region 233 may be a DC biased plasma formed with the pedestal acting as an electrode. Plasma may be present in chamber plasma region 215 to produce the radical precursors from an inflow of, for example, a fluorine-containing precursor or other precursor. An AC voltage typically in the radio frequency (RF) range may be applied between the conductive top portion of the processing chamber, such as faceplate 217, and showerhead 225 and/or ion suppressor 223 to ignite a plasma in chamber plasma region 215 during deposition. An RF power supply may generate a high RF frequency of 13.56 MHz but may also generate other frequencies alone or in combination with the 13.56 MHz frequency.

FIG. 2B shows a detailed view 253 of the features affecting the processing gas distribution through faceplate 217. As shown in FIGS. 2A and 2B, faceplate 217, cooling plate 203, and gas inlet assembly 205 intersect to define a gas supply region 258 into which process gases may be delivered from gas inlet 205. The gases may fill the gas supply region 258 and flow to first plasma region 215 through apertures 259 in faceplate 217. The apertures 259 may be configured to direct flow in a substantially unidirectional manner such that process gases may flow into processing region 233, but may be partially or fully prevented from backflow into the gas supply region 258 after traversing the faceplate 217.

The gas distribution assemblies such as showerhead 225 for use in the processing chamber section 200 may be referred to as dual channel showerheads (DCSH) and are additionally detailed in the embodiments described in FIG. 3. The dual channel showerhead may provide for etching processes that allow for separation of etchants outside of the processing region 233 to provide limited interaction with chamber components and each other prior to being delivered into the processing region.

The showerhead 225 may comprise an upper plate 214 and a lower plate 216. The plates may be coupled with one another to define a volume 218 between the plates. The coupling of the plates may be so as to provide first fluid channels 219 through the upper and lower plates, and second fluid channels 221 through the lower plate 216. The formed channels may be configured to provide fluid access from the volume 218 through the lower plate 216 via second fluid channels 221 alone, and the first fluid channels 219 may be fluidly isolated from the volume 218 between the plates and the second fluid channels 221. The volume 218 may be fluidly accessible through a side of the gas distribution assembly 225.

FIG. 3 is a bottom view of a showerhead 325 for use with a processing chamber according to embodiments. Showerhead 325 may correspond with the showerhead 225 shown in FIG. 2A. Through-holes 365, which show a view of first fluid channels 219, may have a plurality of shapes and configurations in order to control and affect the flow of precursors through the showerhead 225. Small holes 375, which show a view of second fluid channels 221, may be distributed substantially evenly over the surface of the showerhead, even amongst the through-holes 365, and may help to provide more even mixing of the precursors as they exit the showerhead than other configurations.

FIG. 4 shows a schematic cross-sectional view of an exemplary processing system 400 according to embodiments of the present technology. System 400 may include variations on the chamber illustrated in FIG. 2, and may include some or all of the components illustrated in that figure. System 400 may include a processing chamber 405 and a remote plasma unit 410. The remote plasma unit 410 may be coupled with processing chamber 405 with one or more components. The remote plasma unit 410 may be coupled with one or more of an adapter 415, an isolator 420, or a mixing manifold 425. Mixing manifold 425 may be coupled with a top of processing chamber 405, and may be coupled with an inlet to processing chamber 405.

Adapter 415 may be coupled with remote plasma unit 410 at a first end 411, and may be coupled with isolator 420 at a second end 412 opposite first end 411. Through adapter 415 may be defined one or more channels. At first end 411 may be defined an opening or port to a first channel or a central channel 413. Central channel 413 may be centrally defined within adapter 415, and may be characterized by a first cross-sectional surface area in a direction normal to a central axis through adapter 415, which may be in the direction of flow from the remote plasma unit 410. A diameter of central channel 413 may be equal to or in common with an exit port from remote plasma unit 410. Central channel 413 may be characterized by a length from the first end 411 to the second end 412. Central channel 413 may extend through adapter 415 a length less than the length from first end 411 to second end 412. For example, central channel 413 may extend less than halfway of the length from the first end 411 to the second end 412, central channel 413 may extend halfway of the length from the first end 411 to the second end 412, central channel 413 may extend more than halfway of the length from the first end 411 to the second end 412, or central channel 413 may extend about halfway of the length from the first end 411 to the second end 412 of adapter 415.

Central channel 413 may extend to a transition 414 within adapter 415. The transition may include a solid block extending across part of central channel 413, or transition 414 may include an orifice plate defining additional access through the adapter 415, or transition 414 may include any other physical material that at least partially blocks flow through central channel 413. Transition 414 may provide access to one or more second channels 416, which may extend from transition 414 to second end 412. The second channels 416 may be characterized by a second cross-sectional surface area in a direction normal to the central axis through adapter 415. The second cross-sectional surface area may be less than the first cross-sectional surface area in embodiments. Second channels 416 may extend to an exit from adapter 415 at second end 412, and may provide egress from adapter 415 for a precursor, such as plasma effluents, delivered from remote plasma unit 410 into adapter 415 through central channel 413.

Second channels 416 may include an annular or semi-annular channel defined about a central axis in the direction of flow through adapter 415. Second channels 416 may also include a plurality of channels defined radially about a central axis in the direction of flow through adapter 415 that provide fluid access from central channel 413, and extend from central channel 413 to second end 412. Transition 414 may define a plurality of orifices about an exterior of transition 414, and may be characterized as an orifice plate having a solid interior region and one or more orifices defined about an exterior region. The orifices may be a single orifice having a crescent or semi-annular shape, or multiple orifices having a circular, ovular, or other geometric shape and that provide access to second channels 416. In embodiments orifices of transition 414 may be characterized by a radius equal to a radius of second channels 416.

Adapter 415 may also define a third channel 418, which may be located between transition 414 and second end 412. Third channel 418 may also provide egress at second end 412, although the egress may be for a separate precursor delivered alternately from the remote plasma unit 410. For example, third channel 418 may be fluidly accessible from a port 417 defined along an exterior surface, such as a side, of adapter 415, which may bypass remote plasma unit 410. Port 417 may be at or below transition 414 along a length of adapter 415. Third channel 418 may deliver the precursor through the adapter 415 and out second end 412. Third channel 418 may be defined in a region of adapter 415 between transition 414 and second end 412. In embodiments, third channel 418 may not be accessible from central channel 413, transition 414, or second channels 416. Third channel 418 may be configured to maintain a precursor fluidly isolated from plasma effluents delivered into central channel 413 from remote plasma unit 410. The precursor may not contact plasma effluents until exiting adapter 415 through second end 412. Third channel 418 may include one or more channels defined in adapter 415. Third channel 418 may be centrally located within adapter 415, and may be associated with second channels 416. For example, second channels 416 may be concentrically aligned about third channel 418 in embodiments. Second channels 416 may also be disposed proximate third channels 418. Adapter 415 may also define one or more apertures 419, which may allow coupling of the adapter to or through isolator 420.

Isolator 420 may be coupled with second end 412 of adapter 415 in embodiments. Isolator 420 may be or include an annular member about an isolator channel 421. Isolator channel 421 may be axially aligned with a central axis in the direction of flow through adapter 415. Isolator channel 421 may be characterized by a third cross-sectional area in a direction normal to a direction of flow through isolator 420. The third cross-sectional area may be equal to, greater than, or less than the first cross-sectional area of central channel 413. In embodiments, isolator channel 421 may be characterized by a diameter greater than, equal to, or about the same as a diameter of central channel 413 through adapter 415. Isolator channel 421 may provide fluid access from second channels 416 and may also provide fluid access from third channel 418. In embodiments, isolator channel 421 may provide a first region of mixing for plasma effluents delivered from remote plasma unit 410 and an additional precursor delivered to port 417 and through third channel 418. Isolator 420 may also define one or more channels 422, which may allow coupling to or through isolator 420 with adapter 415 and/or mixing manifold 425. Channels 422 may be axially aligned with apertures 419 described above, which together may provide coupling points, such as bolt holes, for example, through which the components may be secured.

Isolator 420 may be made of a similar or different material from adapter 415, mixing manifold 425, or any other chamber component. In some embodiments, while adapter 415 and mixing manifold 425 may be made of or include aluminum, including oxides of aluminum, treated aluminum on one or more surfaces, or some other material, isolator 420 may be or include a material that is less thermally conductive than other chamber components. In some embodiments, isolator 420 may be or include a ceramic, plastic, or other thermally insulating component configured to provide a thermal break between the remote plasma unit 410 and the chamber 405. During operation, remote plasma unit 410 may be cooled or operate at a lower temperature relative to chamber 405, while chamber 405 may be heated or operate at a higher temperature relative to remote plasma unit 410. Providing a ceramic or thermally insulating isolator 420 may prevent or limit thermal, electrical, or other interference between the components.

Mixing manifold 425 may be coupled with isolator 420 at a first end 423, and may be coupled with chamber 405 at a second end 424. Mixing manifold 425 may define an inlet 427 at first end 423. Inlet 427 may provide fluid access from isolator channel 421, and inlet 427 may be characterized by a diameter equal to or about the same as a diameter of isolator channel 421. Inlet 427 may define a portion of a channel 426 through mixing manifold 425, and the channel 426 may be composed of one or more sections defining a profile through channel 426. Inlet 427 may be a first section in the direction of flow through channel 426 of mixing manifold 425. Inlet 427 may be characterized by a length that may be less than half a length in the direction of flow of mixing manifold 425. The length of inlet 427 may also be less than a third of the length of mixing manifold 425, and may be less than one quarter the length of mixing manifold 425 in embodiments.

Inlet 427 may extend to a second section of channel 426, which may be or include a tapered section 428. Tapered section 428 may extend from a first diameter equal to or similar to a diameter of inlet 427 to a second diameter less than the first diameter. In some embodiments, the second diameter may be about or less than half the first diameter. Tapered section 428 may be characterized by an angle of taper of greater than or about 10%, greater than or about 20%, greater than or about 30%, greater than or about 40%, greater than or about 50%, greater than or about 60%, greater than or about 70%, greater than or about 80%, greater than or about 90%, greater than or about 100%, greater than or about 150%, greater than or about 200%, greater than or about 300%, or greater in embodiments.

Tapered section 428 may transition to a third region of channel 426, which may be a flared section 429. Flared section 429 may extend from tapered section 428 to an outlet of mixing manifold 425 at second end 424. Flared section 429 may extend from a first diameter equal to the second diameter of tapered section 428 to a second diameter greater than the first diameter. In some embodiments, the second diameter may be about or greater than double the first diameter. Flared section 429 may be characterized by an angle of flare of greater than or about 10%, greater than or about 20%, greater than or about 30%, greater than or about 40%, greater than or about 50%, greater than or about 60%, greater than or about 70%, greater than or about 80%, greater than or about 90%, greater than or about 100%, greater than or about 150%, greater than or about 200%, greater than or about 300%, or greater in embodiments.

Flared section 429 may provide egress to precursors delivered through mixing manifold 425 through second end 424 via an outlet 431. The sections of channel 426 through mixing manifold 425 may be configured to provide adequate or thorough mixing of precursors delivered to the mixing manifold, before providing the mixed precursors into chamber 405. Unlike conventional technology, by performing the etchant or precursor mixing prior to delivery to a chamber, the present systems may provide an etchant having uniform properties prior to being distributed about a chamber and substrate. In this way, processes performed with the present technology may have more uniform results across a substrate surface.

Mixing manifold 425 may also define recesses 433, which may allow coupling of the adapter 415, the isolator 420, and the mixing manifold 425. Recesses 433 may be axially aligned with channels 422 and apertures 419, which may allow coupling of the three component with bolts, fasteners, or any other threaded or non-threaded components capable of providing compressive force to the three components for securing with o-rings or elastomeric members on either side of isolator 420, located within channels defined in adapter 415 and mixing manifold 425.

Chamber 405 may include a number of components in a stacked arrangement. The chamber stack may include a gasbox 450, a blocker plate 460, a faceplate 470, an ion suppression element 480, and a lid spacer 490. The components may be utilized to distribute a precursor or set of precursors through the chamber to provide a uniform delivery of etchants or other precursors to a substrate for processing.

Gasbox 450 may define a chamber inlet 452. A central channel 454 may be defined through gasbox 450 to deliver precursors into chamber 405. Inlet 452 may be aligned with outlet 431 of mixing manifold 425. Inlet 452 and/or central channel 454 may be characterized by a similar diameter in embodiments. Central channel 454 may extend through gasbox 450 and be configured to deliver one or more precursors into a volume 457 defined from above by gasbox 450. Gasbox 450 may include a first surface 453, such as a top surface, and a second surface 455 opposite the first surface 453, such as a bottom surface of gasbox 450. Top surface 453 may be a planar or substantially planar surface in embodiments. Coupled with top surface 453 may be a heater 448.

Heater 448 may be configured to heat chamber 405 in embodiments, and may conductively heat each lid stack component. Heater 448 may be any kind of heater including a fluid heater, electrical heater, microwave heater, or other device configured to deliver heat conductively to chamber 405. In some embodiments, heater 448 may be or include an electrical heater formed in an annular pattern about first surface 453 of gasbox 450. The heater may be defined across the gasbox 450, and around mixing manifold 425. The heater may be a plate heater or resistive element heater that may be configured to provide up to, about, or greater than about 2,000 W of heat, and may be configured to provide greater than or about 2,500 W, greater than or about 3,000 W, greater than or about 3,500 W, greater than or about 4,000 W, greater than or about 4,500 W, greater than or about 5,000 W, or more.

Heater 448 may be configured to produce a variable chamber component temperature up to, about or greater than about 50° C., and may be configured to produce a chamber component temperature greater than or about 75° C., greater than or about 100° C., greater than or about 150° C., greater than or about 200° C., greater than or about 250° C., greater than or about 300° C., or higher in embodiments. Heater 448 may be configured to raise individual components, such as the ion suppression element 480 to any of these temperatures to facilitate processing operations, such as an anneal. In some processing operations, a substrate may be raised toward the ion suppression element 480 for an annealing operation, and heater 448 may be adjusted to conductively raise the temperature of the heater to any particular temperature noted above, or within any range of temperatures within or between any of the stated temperatures.

Second surface 455 of gasbox 450 may define a profile of the gasbox including a recessed ledge 456 extending from a lip 458 to a drop portion 459, which may define a thickness of the gasbox 450. Drop portion 459 may be the portion of gasbox 450 defining volume 457 from above. Gasbox 450 may also define a plurality of recesses 461, which may allow coupling of the blocker plate 460 to the gasbox 450. Blocker plate 460 may be characterized by a diameter equal to or similar to a diameter of drop portion 459. Blocker plate 460 may define a plurality of apertures 463 through blocker plate 460, which may allow distribution of precursors, such as etchants, from volume 457, and may begin distributing precursors through chamber 405 for a uniform delivery to a substrate. Blocker plate 460 may be characterized by a raised annular section 465 at an external diameter of the blocker plate 460. Raised annular section 465 may provide structural rigidity for the blocker plate 460, and may define sides of volume 457 in embodiments, which may be an outer or exterior radius in cylindrical configurations. Blocker plate 460 may also define a bottom of volume 457 from below. Volume 457 may allow distribution of precursors from central channel 454 of gasbox 450 before passing through apertures 463 of blocker plate 460. Blocker plate 460 may also define a plurality of apertures 467, which may be axially aligned with recesses 461 of gasbox 450. Bolts or other threaded or non-threaded coupling devices may be used from an underside of blocker plate 460 to couple blocker plate 460 to drop portion 459 or a bottom side of gasbox 450.

Faceplate 470 may include a first surface 472 and a second surface 474 opposite the first surface 472. Faceplate 470 may be coupled with gasbox 450 at first surface 472, which may engage lip 458 of gasbox 450. Faceplate 470 may define a ledge 473 at an interior of first surface 472, extending to an internal region 477 defined within faceplate 470. Faceplate 470 may be characterized along a vertical cross-section of the faceplate 470 by a first diameter and a second diameter less than the first diameter. The first diameter may be the outer diameter of first surface 472 and second surface 474, and the second diameter may be an inner diameter of the internal region in between the first surface 472 and second surface 474, such as mid region 475 as illustrated. An external profile of the faceplate 470 may include a C-shaped external profile about the faceplate 470.

As shown in the figure, blocker plate 460 and gasbox 450 may extend into or be positioned within the internal region 477 of faceplate 470. An outer diameter of the blocker plate 460 may be within 10% or less of an inner diameter of the internal region 477 of faceplate 470, and may be less than or about 8%, less than or about 6%, less than or about 5%, less than or about 4%, less than or about 3%, less than or about 2%, less than or about 1%, less than or about 0.5%, less than or about 0.1%, or less in embodiments. By maintaining a limited spacing or distance between drop portion 459 of gasbox 450 and internal region 477 of faceplate 470, particle accumulation may be minimized, which may reduce cleaning and replacement time, as well as reduce contaminant distribution during processing. Faceplate 470 may define a plurality of channels 476 through the faceplate, such as previously described with chamber 200. A sample of channels 476 are illustrated, although many more such channels than shown may be included in embodiments.

Ion suppression element 480 may be positioned proximate the second surface 474 of faceplate 470, and may be coupled with faceplate 470 at second surface 474. Ion suppression element 480 may be similar to ion suppressor 223 described above, and may be configured to reduce ionic migration into a processing region of chamber 405 housing a substrate. In embodiments, gasbox 450, faceplate 470, and ion suppression element 480 may be coupled together, and in embodiments may be directly coupled together. By directly coupling the components, heat generated by heater 448 may be conducted through the components to maintain a particular chamber temperature that may be maintained with less variation between components. Ion suppression element 480 may also contact lid spacer 490, which together may at least partially define a plasma processing region in which a substrate is maintained during processing.

Turning to FIG. 5A is illustrated a schematic perspective view of a blocker plate 460 according to embodiments of the present technology. As illustrated, blocker plate 460 includes a raised annular section 465 through which a plurality of apertures 467 are defined. Blocker plate 460 may be coupled with gasbox 450 by coupling through these apertures. By utilizing coupling along an exterior region, blocker plate 460 may maintain a uniform central profile, unlike many conventional plates that may be coupled to components through central bosses. Central coupling may affect the flow profile through the blocker plate 460, which may limit or affect uniformity of distribution through the processing chamber. Apertures 463 may be defined through a central region of blocker plate 460, and may be uniformly distributed across the blocker plate 460. The apertures 463 may be a uniform size, or may have different sizes based on their location.

FIG. 5B illustrates a schematic flow profile through a blocker plate 500 according to embodiments of the present technology. As illustrated, blocker plate 500 does not include any central boss or apertures for coupling the blocker plate, and thus the flow profile through blocker plate 500 is uniform across the surface at different radius measurements. The difference in flow profile from a central region may be due to the central delivery of precursors from a gasbox as previously described, which may provide a concentration before lateral distribution across the plate and through the apertures. By removing any centrally located impediments to flow, a uniform distribution of precursors may be delivered through blocker plate 460 towards a processing region and substrate.

FIG. 6 shows a schematic partial cross-sectional view of an exemplary processing chamber according to embodiments of the present technology. The figure may include a partial close-up view of FIG. 4. As illustrated, the figure includes gasbox 450, blocker plate 460, faceplate 470, ion suppression element 480, and lid spacer 490. FIG. 6 illustrates additional coupling aspects of the chamber components, including o-rings or elastomeric elements providing sealing capabilities between the components. As illustrated, gasbox 450 defines a plurality of trenches 605 a, 605 b defined in the gasbox 450. The trenches 605 may be annular trenches defined about the gasbox 450. Elastomeric elements may be positioned within the trenches to provide a seal between the gasbox 450 and faceplate 470. Although two trenches 605 are shown, it is to be understood that any number of trenches may be included within the gasbox 450.

Ion suppression element 480 also defines a plurality of trenches 610 a, 610 b along a surface in contact with faceplate 470. The trenches 610 may be annular trenches similar to those discussed above for gasbox 450. Trenches 605 and trenches 610 may be vertically aligned in embodiments, and may be associated with bolts or other coupling elements incorporated through the components to provide connections. Ion suppression element 480 may also define a plurality of trenches 615 a, 615 b on a second surface in contact with lid spacer 490.

FIG. 7 shows operations of a method 700 of delivering precursors through a processing chamber according to embodiments of the present technology. Method 700 may be performed in chamber 200 or chamber 400, and may allow improved precursor mixing externally to the chamber, while protecting components from etchant damage. While components of a chamber may be exposed to etchants that may cause wear over time, the present technology may limit these components to those that may be more easily replaced and serviced. For example, the present technology may limit exposure of internal components of a remote plasma unit, which may allow particular protection to be applied to the remote plasma unit.

Method 700 may include forming a remote plasma of a fluorine-containing precursor in operation 705. The precursor may be delivered to a remote plasma unit to be dissociated to produce plasma effluents. In embodiments, the remote plasma unit may be coated or lined with an oxide or other material that may withstand contact with the fluorine-containing effluents. In embodiments, aside from carrier gases, no other etchant precursors may be delivered through the remote plasma unit, which may protect the unit from damage. Other embodiments configured to produce plasma effluents of a different etchant may be lined with a different material that may be inert to that precursor.

At operation 710, plasma effluents of the fluorine-containing precursor may be flowed into an adapter coupled with the remote plasma unit. At operation 715, a hydrogen-containing precursor may be flowed into the adapter. The adapter may be configured to maintain the plasma effluents of the fluorine-containing precursor and the hydrogen-containing precursor fluidly isolated through the adapter. At operation 720, the plasma effluents of the fluorine-containing precursor and the hydrogen-containing precursor may be flowed into a mixing manifold configured to mix the plasma effluents of the fluorine-containing precursor and the hydrogen-containing precursor prior to delivering the mixed precursors or etchant produced into a semiconductor processing chamber. Additional components described elsewhere may be used to control delivery and distribution of the etchants as previously discussed. It is to be understood that the precursors identified are only examples of suitable precursors for use in the described chambers. The chambers and materials discussed throughout the disclosure may be used in any number of other processing operations that may benefit from separating precursors and mixing them prior to delivery into a processing chamber.

In the preceding description, for the purposes of explanation, numerous details have been set forth in order to provide an understanding of various embodiments of the present technology. It will be apparent to one skilled in the art, however, that certain embodiments may be practiced without some of these details, or with additional details.

Having disclosed several embodiments, it will be recognized by those of skill in the art that various modifications, alternative constructions, and equivalents may be used without departing from the spirit of the embodiments. Additionally, a number of well-known processes and elements have not been described in order to avoid unnecessarily obscuring the present technology. Accordingly, the above description should not be taken as limiting the scope of the technology.

Where a range of values is provided, it is understood that each intervening value, to the smallest fraction of the unit of the lower limit, unless the context clearly dictates otherwise, between the upper and lower limits of that range is also specifically disclosed. Any narrower range between any stated values or unstated intervening values in a stated range and any other stated or intervening value in that stated range is encompassed. The upper and lower limits of those smaller ranges may independently be included or excluded in the range, and each range where either, neither, or both limits are included in the smaller ranges is also encompassed within the technology, subject to any specifically excluded limit in the stated range. Where the stated range includes one or both of the limits, ranges excluding either or both of those included limits are also included.

As used herein and in the appended claims, the singular forms “a”, “an”, and “the” include plural references unless the context clearly dictates otherwise. Thus, for example, reference to “a layer” includes a plurality of such layers, and reference to “the precursor” includes reference to one or more precursors and equivalents thereof known to those skilled in the art, and so forth.

Also, the words “comprise(s)”, “comprising”, “contain(s)”, “containing”, “include(s)”, and “including”, when used in this specification and in the following claims, are intended to specify the presence of stated features, integers, components, or operations, but they do not preclude the presence or addition of one or more other features, integers, components, operations, acts, or groups. 

1. A semiconductor processing system comprising: a processing chamber; a remote plasma unit coupled with the processing chamber; and an adapter coupled with the remote plasma unit, wherein the adapter comprises a first end and a second end opposite the first end, wherein the adapter defines an opening to a central channel at the first end, wherein the central channel is characterized by a first cross-sectional surface area, wherein the adapter defines an exit from a second channel at the second end, wherein the adapter defines a transition between the central channel and the second channel within the adapter between the first end and the second end, wherein the adapter defines a third channel between the transition and the second end of the adapter, and wherein the third channel is fluidly isolated from the central channel and the second channel within the adapter.
 2. The semiconductor processing system of claim 1, wherein the second channel is characterized by a second cross-sectional area less than the first cross-sectional area.
 3. The semiconductor processing system of claim 1, wherein the second channel comprises a plurality of channels extending from the central channel.
 4. The semiconductor processing system of claim 1, wherein the adapter further defines a port providing access to the third channel.
 5. The semiconductor processing system of claim 1, further comprising an isolator coupled between the adapter and the processing chamber, wherein the isolator comprises an annular member about an isolator channel, and wherein the isolator channel is fluidly coupled with the second channel and the third channel.
 6. The semiconductor processing system of claim 5, wherein the isolator comprises a ceramic.
 7. The semiconductor processing system of claim 5, further comprising a mixing manifold coupled between the isolator and the processing chamber.
 8. The semiconductor processing system of claim 7, wherein the mixing manifold is characterized by an inlet having a diameter equal to a diameter of the isolator channel.
 9. The semiconductor processing system of claim 8, wherein the inlet of the mixing manifold transitions to a tapered section of the mixing manifold.
 10. The semiconductor processing system of claim 9, wherein the tapered section of the mixing manifold transitions to a flared section of the mixing manifold extending to an outlet of the mixing manifold.
 11. A semiconductor processing system comprising: a remote plasma unit; and a processing chamber comprising: a gasbox defining a central channel, a blocker plate coupled with the gasbox, wherein the blocker plate defines a plurality of apertures through the blocker plate, a faceplate coupled with the gasbox at a first surface of the faceplate, and an ion suppression element coupled with the faceplate at a second surface of the faceplate opposite the first surface of the faceplate.
 12. The semiconductor processing system of claim 11, further comprising a heater coupled externally to the gasbox about a mixing manifold coupled to the gasbox.
 13. The semiconductor processing system of claim 11, wherein the gasbox defines a volume from above and the blocker plate defines the volume from below and about an outer radius.
 14. The semiconductor processing system of claim 11, wherein the gasbox, faceplate, and ion suppression element are directly coupled together.
 15. The semiconductor processing system of claim 11, wherein the faceplate is characterized along a vertical cross-section of the faceplate by a first diameter and a second diameter, wherein the faceplate defines a ledge on an interior of the first surface of the faceplate extending to an internal region of the faceplate characterized by the second diameter.
 16. The semiconductor processing system of claim 15, wherein the blocker plate extends into the internal region of the faceplate, and wherein the blocker plate is characterized by a diameter within five percent of the second diameter.
 17. The semiconductor processing system of claim 15, wherein the first surface of the faceplate and the second surface of the faceplate are characterized by the first diameter.
 18. The semiconductor processing system of claim 17, wherein the gasbox defines a plurality of annular trenches along a surface of the gasbox in contact with the faceplate, and wherein the ion suppression element defines a plurality of annular trenches along a surface of the ion suppression element in contact with the faceplate.
 19. A method of delivering precursors through a semiconductor processing system, the method comprising: forming a plasma of a fluorine-containing precursor in a remote plasma unit; flowing plasma effluents of the fluorine-containing precursor into an adapter; flowing a hydrogen-containing precursor into the adapter, wherein the adapter is configured to maintain the plasma effluents of the fluorine-containing precursor and the hydrogen-containing precursor fluidly isolated through the adapter; and flowing the plasma effluents of the fluorine-containing precursor and the hydrogen-containing precursor into a mixing manifold configured to mix the plasma effluents of the fluorine-containing precursor and the hydrogen-containing precursor.
 20. The method of delivering precursors through a semiconductor processing system of claim 19, further comprising flowing the mixed plasma effluents of the fluorine-containing precursor and the hydrogen-containing precursor into a processing chamber. 